39. A Carboranyl Electrolyte Enabling Highly Reversible Sodium Metal Anodes via a 'Fluorine-Free' SEI

A. W. Tomich, J. Park, S.B. Son, E. P. Kamphaus, X. Lyu, F. Dogan, V. Carta, J. Gim, T. Li, L. Cheng, E. Lee, V. Lavallo*,

C. S. Johnson*.
Angew. Chem. Int. Ed., 2022 , 61, e202208158.
38. Fusing 10-vertex closo-Carborane Anions with N-Heterocyclic Carbenes

V. Tej, S. Lee, I. Banda, A. Gregory, S. McArthur, S. P. Fisher, V. Lavallo*.
Chem. Commun., 2022, 58, 10580-10582.
(Invited: Pioneering Investigators)
37. Searching for the Truth: Elemental Analysis - A Powerful but Often Poorly Executed Technique

S. Proctor, S. O. Lovera, A. W. Tomich, V. Lavallo*.
ACS Cent. Sci., 2022, 8, 7, 874–876.
(Invited)

*See Also:
Science, 2022, Combustion Analysis: That Voodoo That We Do

*See Also:
ACS Cent. Sci., 2022, Chemists Debate the Value of Elemental Analysis
36. Cesium Carbonate Mediated C-H Functionalization of Perhalogenated 12-vertex Carborane Anions

S. O. Lovera, A. L. Bagsdasarian, J. Guo, H. M. Nelson*, V. Lavallo*.
Chem. Commun., 2022, 58, 4060-4062.
(Invited: Boron Chemistry Special Edition)
35. Book Chapter: Ligands Featuring Covalently Tethered Moderate to Weakly Coordinating Anions

A. W. Tomich, V. Tej; S. O. Lovera, I. Banda, M. Asay*, S. P. Fisher*, V. Lavallo*.
Comprehensive Organometallic Chemistry IV, 2022, In Press.
(Invited)
34. Strongly Coordinating Ligands to Form Weakly Coordinating yet Functional Organometallic Anions

S. P. Fisher, S. McArthur, V. Tej, S. Lee, A. Chan, I. Banda, A. Gregory, K. Berkely, C. Tsay, A. Rheingold,

G. Guisado-Barrios, V. Lavallo*.
J. Am. Chem. Soc., 2020, 142, 1, 251-256.
33. Understanding Superionic Conductivity in Lithium and Sodium Salts of Weakly Coordinating
Closo-Hexahalocarbaborate Anions

M. Jørgensen, P. Shea, A. W. Tomich, J. Varley, M. Bercx, S. O. Lovera, R. Cerný, W. Zhou, T. J. Udovic, V. Lavallo*,

T. Jensen*, B. Wood*, V. Stavila*.
Chem. Mater., 2020, 32, 4, 1475-1487.
32. Characterization of Reactive Organometallic Species via MicroED

C. Jones, M. Asay, L. J. Kim, J. Kleinsasser, A. Saha, T. Fulton, K. Berkly, D. Cascio, A. Malyutin, M. Conley, B. Stoltz*, V.

Lavallo*, J. Rodriguez*, H. M. Nelson*.
ACS Cent. Sci., 2019, 5, 9, 1507-1513.
31. The Debut of Chiral Cyclic (Alkyl)(Amino)Carbenes (CAACs) in Enantioselective Catalysis

D. Pichon, M. Soleilhavoup, J. Morvan, G. P. Junor, T. Vives, C. Crévisy, V. Lavallo, J. M. Campagne, M. Mauduit*, R.

Jazzar*, G. Bertrand*.
Chem. Sci., 2019, 10, 7807-7811.
30. Vinyl Carbocations Generated Under Basic Conditions and Their Intramolecular C–H Insertion Reactions

B. Wigman, S. Popov, A. L. Bagdasarian, B. Shao, T. R. Benton, C. G. Williams, S. P. Fisher, V. Lavallo*, K. N. Houk*,

H. M. Nelson*.
J. Am. Chem. Soc., 2019, 141, 23, 9140-9144.
29. A Comparative Study of Mg(CB11H12)2 and Mg(TFSI)2 at the Magnesium/Electrolyte Interface

R. Jay, A. W. Tomich, J. Zhang, Y. Zhao, A. D. Gorostiza, V. Lavallo*, J. Guo*
ACS Appl. Mater. Interfaces, 2019, 11 (12), pp 11414–11420
28. Non-Classical Applications of Closo-Carborane Anions: From Main Group Chemistry and Catalysis to Energy
Storage

S. P. Fisher, A. W. Tomich, S. O. Lovera, J. Kleinsasser, J. Guo, M. Asay*, H. M. Nelson*, V. Lavallo*,
Chem. Rev., 2019, 119, 14, 8262-8290.
(Invited)
27. Teaching an Old Dog New Tricks: New Directions in Fundamental and Applied closo-Carborane Anion Chemistry

S. P. Fisher, A. W. Tomich, J. Guo, V. Lavallo*,
Chem. Comm., 2019, 55, 1684-1701.
(Invited)
26. The First example of a "Click" Reaction with a Carboranyl Azide and an Olefin

Uday B. Chauhan, A. W. Tomich*, V. Lavallo*,
Tetrahedron,
2019, 75, 10, 1323-1325.
(Invited: Main Group Special Issue)
25. Ethylene Oligomerization and Polymerization by Palladium(II) Methyl Complexes Supported by Phosphines
Bearing a Perchlorinated 10-Vertex closo-Carborane Anion Substituent

J. F. Kleinsasser, E. Reinhart, J. Estrada, R. Jordan*, V. Lavallo*,
Organometallics, 2018, 37, 24, 4773–4783.
24. Synthesis of an Anionic Au(I) Hydroamination Precatalyst Supported by Charged Hydrido-Carboranyl Phosphine
Ligands

J. F. Kleinsasser, S. E. Lee, C. A. Lugo, V. Tej, S. G. McArthur, V. Lavallo*,
Polyhedron, 2018, 156, 245-248.
(Invited: In celebration of Bill Jones's 65th birthday)
23. Reversible Silver Electrodeposition from Boron Cluster Ionic Liquid (BCIL) Electrolytes

R. Dziedzic, M. Waddington, S. E. Lee; J. F. Kleinsasser, J. Plumley, W. Ewing, B. Bosley*, V. Lavallo*, T. Peng*,

A. Spokoyny*,
ACS Appl. Mater. Interfaces, 2018, 10, 8, 6825–6830.
22. Fusing Dicarbollide Ions with N-Heterocyclic Carbenes

J. Estrada, V. Lavallo*,
Angew. Chem. Int. Ed., 2017, 56, 9906-9909.

21. On the Reactivity of the Carba-closo-Dodecaborate Anion with the Trityl Cation

J. F. Kleinsasser, S. P. Fisher, F.S. Tham, V. Lavallo*,
Eur. J. Inorg. Chem., 2017, 4417–4419
(Invited: Boron
Special Issue).
20. Below the 12-Vertex: 10-Vertex Carborane Anions as NonCorrosive, Halide Free, Electrolytes for Rechargeable
Mg Batteries

S.G. McArthur, R. Jay, L. Geng, J. Guo*, V. Lavallo*,
Chem. Commun., 2017, 53, 4453-4456.